省部共建国重室王开拓团队在CTAB改性偏高岭土聚合物微球对TcO4−/ReO4−的选择性吸附和回收方面取得进展-特色金属材料与组合结构全寿命安全国家重点实验室

省部共建国重室王开拓团队在CTAB改性偏高岭土聚合物微球对TcO4−/ReO4−的选择性吸附和回收方面取得进展

2024年05月20日 11:39 点击：[]

近日，省部共建国重室王开拓团队在CTAB改性偏高岭土聚合物微球对TcO4−/ReO4−的选择性吸附和回收方面取得进展，相关工作以"CTAB modified metakaolin-based geopolymer microspheres for the selective adsorption and recovery of TcO₄⁻/ReO₄⁻"为题，发表在《Separation and Purification Technology》上。

随着放射性废水的增加，有效去除放射性废水中的TcO₄⁻是一个重大挑战。目前，阳离子金属有机框架(MOFs)、阳离子共价有机框架(COFs)、阳离子聚合物网络(CPNs)和多孔有机聚合物材料(POPs)均能有效去除TcO₄⁻，但制备工艺繁琐，成本高，限制了其实际应用。本文采用分散-成球-固化和真空灌注的方法，简单快速地合成了高效、低成本的ctab改性偏高岭土聚合物微球(CTAB@MGMs)，该微球对ReO₄⁻具有优异的吸附性能。CTAB@MGMs具有快速的吸附动力学(10分钟内达到平衡)，广泛的pH适用范围(2-10)和对竞争离子(PO₄³⁻，SO₄²⁻，NO₃⁻，Cl⁻)和实际水(自来水，地表水，海水)的高选择性。重要的是，被吸附的样品可以被乙醇完全解吸，mgm可以回收而不会产生性能衰减。同时，通过解吸液的自旋蒸发，实现了乙醇的再循环，生成了一种新型化合物CTA-ReO₄。本文首次对CTA-ReO₄(CCDC编号:2282273)的晶体结构进行了分析和报道，揭示了离子交换后ReO₄⁻通过静电和与季铵盐的配位增效去除的机理。CTAB@MGMs是一种低成本、新颖、可重复使用的吸附剂，具有从放射性废水中去除TcO₄⁻的潜在用途。

上一条：省部共建国重室陈正教授团队在含硫酸盐混凝土中钢筋的脱钝化机理研究中取得研究进展下一条：省部共建国重室陈正教授团队在-NH2和-COO-官能团对混凝土孔溶液中钢钝化的影响研究中取得研究进展

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'tid' => '1', 'pid' => '11', 'mid' => 'news', 'pids' => '0,11', 'name' => '科研队伍', 'dirname' => 'keyanduiwu', 'pdirname' => 'shouye/', 'child' => 1, 'disabled' => '0', 'ismain' => 1, 'childids' => '24,51,52,53,54', 'thumb' => '', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'getchild' => '0', 'notedit' => '0', 'urlrule' => 0, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '20', 'mpagesize' => '20', 'page' => 'page.html', 'list' => 'listimg.html', 'category' => 'listimg.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => NULL, 'module_field' => NULL, 'html' => 0, ), 'displayorder' => '0', 'pcatpost' => 0, 'topid' => '11', 'catids' => array ( 0 => '24', 1 => '51', 2 => '52', 3 => '53', 4 => '54', ), 'is_post' => 0, 'url' => 'http://wei.vialancer.com/index.php?c=category&id=24', 'total' => '请使用count标签查询', 'field' => array ( ), ), 25 => array ( 'id' => '25', 'tid' => '1', 'pid' => '11', 'mid' => 'news', 'pids' => '0,11', 'name' => '研究团队', 'dirname' => 'yjtd', 'pdirname' => 'shouye/', 'child' => 0, 'disabled' => '0', 'ismain' => 1, 'childids' => 25, 'thumb' => '', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'getchild' => '0', 'notedit' => '0', 'urlrule' => 0, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '20', 'mpagesize' => '20', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => NULL, 'module_field' => NULL, 'html' => 0, ), 'displayorder' => '0', 'pcatpost' => 0, 'topid' => '11', 'catids' => array ( 0 => '25', ), 'is_post' => 1, 'url' => 'http://wei.vialancer.com/index.php?c=category&id=25', 'total' => '请使用count标签查询', 'field' => array ( ), ), )
urlrule	'/index.php?c=show&id=27&page=[page]'
fix_html_now_url	''
my_web_url	'http://wei.vialancer.com/index.php?c=show&id=27'
get	array ( 'c' => 'show', 'id' => '27', )

省部共建国重室王开拓团队在CTAB改性偏高岭土聚合物微球对TcO4−/ReO4−的选择性吸附和回收方面取得进展

友情链接

联系我们

联系我们

Database (5 Queries across 0 Connection)

Views

运行时间：0.01ms

模板文件

引用提示

模板变量

Files ( 148 )

Routes

Events

History

View Data

Session User Data

Request ( HTTP/1.1 )

$_GET

Headers

Cookies

Response ( 200 - OK )

Headers

System Configuration

App.php	APPPATH/Config/App.php
Auto.php	FCPATH/App/Module/Config/Auto.php
Autoload.php	APPPATH/Config/Autoload.php
AutoloadConfig.php	APPPATH/System/Config/AutoloadConfig.php
Autoloader.php	APPPATH/System/Autoloader/Autoloader.php
BaseBuilder.php	APPPATH/System/Database/BaseBuilder.php
BaseCollector.php	APPPATH/System/Debug/Toolbar/Collectors/BaseCollector.php
BaseConfig.php	APPPATH/System/Config/BaseConfig.php
BaseConnection.php	APPPATH/System/Database/BaseConnection.php
BaseHandler.php	APPPATH/System/Cache/Handlers/BaseHandler.php
BaseResult.php	APPPATH/System/Database/BaseResult.php
BaseService.php	APPPATH/System/Config/BaseService.php
Builder.php	APPPATH/System/Database/MySQLi/Builder.php
Cache.php	APPPATH/Config/Cache.php
Cache.php	APPPATH/Extend/Cache.php
Cache.php	FCPATH/Fcms/Library/Cache.php
CacheFactory.php	APPPATH/System/Cache/CacheFactory.php
CacheInterface.php	APPPATH/System/Cache/CacheInterface.php
Category.php	FCPATH/App/Module/Action/Category.php
CliRenderer.php	APPPATH/System/ThirdParty/Kint/Renderer/CliRenderer.php
CodeIgniter.php	APPPATH/Extend/CodeIgniter.php
CodeIgniter.php	APPPATH/System/CodeIgniter.php
Common.php	APPPATH/System/Common.php
Config.php	APPPATH/System/Config/Config.php
Config.php	APPPATH/System/Database/Config.php
Connection.php	APPPATH/System/Database/MySQLi/Connection.php
ConnectionInterface.php	APPPATH/System/Database/ConnectionInterface.php
Constants.php	APPPATH/Config/Constants.php
Content.php	FCPATH/App/Module/Models/Content.php
Content.php	FCPATH/Fcms/Model/Content.php
ContentSecurityPolicy.php	APPPATH/Config/ContentSecurityPolicy.php
ContentSecurityPolicy.php	APPPATH/System/HTTP/ContentSecurityPolicy.php
Controller.php	APPPATH/Extend/Controller.php
Controller.php	APPPATH/System/Controller.php
Database.php	APPPATH/Config/Database.php
Database.php	APPPATH/System/Database/Database.php
Database.php	APPPATH/System/Debug/Toolbar/Collectors/Database.php
Date.php	FCPATH/Fcms/Field/Date.php
DebugToolbar.php	APPPATH/System/Filters/DebugToolbar.php
DotEnv.php	APPPATH/System/Config/DotEnv.php
Editor.php	FCPATH/Fcms/Field/Editor.php
Events.php	APPPATH/Config/Events.php
Events.php	APPPATH/System/Debug/Toolbar/Collectors/Events.php
Events.php	APPPATH/System/Events/Events.php
Exceptions.php	APPPATH/Config/Exceptions.php
Exceptions.php	APPPATH/Extend/Exceptions.php
Exceptions.php	APPPATH/System/Debug/Exceptions.php
Factories.php	APPPATH/System/Config/Factories.php
Factory.php	APPPATH/System/Config/Factory.php
Field.php	FCPATH/Fcms/Library/Field.php
File.php	FCPATH/Fcms/Field/File.php
FileHandler.php	APPPATH/System/Cache/Handlers/FileHandler.php
FileLocator.php	APPPATH/System/Autoloader/FileLocator.php
Files.php	APPPATH/System/Debug/Toolbar/Collectors/Files.php
FilterInterface.php	APPPATH/System/Filters/FilterInterface.php
Filters.php	APPPATH/Config/Filters.php
Filters.php	APPPATH/System/Filters/Filters.php
Header.php	APPPATH/System/HTTP/Header.php
Helper.php	FCPATH/Fcms/Core/Helper.php
Hook.php	APPPATH/Extend/Hook.php
Hooks.php	FCPATH/App/Module/Config/Hooks.php
Hooks.php	FCPATH/Fcms/Core/Hooks.php
IncomingRequest.php	APPPATH/System/HTTP/IncomingRequest.php
Init.php	APPPATH/Init.php
Init.php	FCPATH/Fcms/Init.php
Input.php	FCPATH/Fcms/Library/Input.php
Kint.php	APPPATH/Config/Kint.php
Kint.php	APPPATH/System/ThirdParty/Kint/Kint.php
Lang.php	FCPATH/Fcms/Library/Lang.php
Logger.php	APPPATH/Config/Logger.php
Logger.php	APPPATH/System/Log/Logger.php
LoggerInterface.php	APPPATH/System/ThirdParty/PSR/Log/LoggerInterface.php
Logs.php	APPPATH/System/Debug/Toolbar/Collectors/Logs.php
Member.php	FCPATH/Fcms/Model/Member.php
Message.php	APPPATH/System/HTTP/Message.php
MessageInterface.php	APPPATH/System/HTTP/MessageInterface.php
MessageTrait.php	APPPATH/System/HTTP/MessageTrait.php
Model.php	APPPATH/Extend/Model.php
Model.php	FCPATH/Fcms/Core/Model.php
Module.php	FCPATH/App/Module/Extends/Home/Module.php
Modules.php	APPPATH/Config/Modules.php
Modules.php	APPPATH/System/Modules/Modules.php
Paths.php	APPPATH/Config/Paths.php
Phpcmf.php	FCPATH/Fcms/Core/Phpcmf.php
Query.php	APPPATH/System/Database/Query.php
QueryInterface.php	APPPATH/System/Database/QueryInterface.php
Related.php	FCPATH/App/Module/Action/Related.php
Renderer.php	APPPATH/System/ThirdParty/Kint/Renderer/Renderer.php
RendererInterface.php	APPPATH/System/View/RendererInterface.php
Request.php	APPPATH/Extend/Request.php
Request.php	APPPATH/System/HTTP/Request.php
RequestInterface.php	APPPATH/System/HTTP/RequestInterface.php
RequestTrait.php	APPPATH/System/HTTP/RequestTrait.php
Response.php	APPPATH/System/HTTP/Response.php
ResponseInterface.php	APPPATH/System/HTTP/ResponseInterface.php
ResponseTrait.php	APPPATH/System/API/ResponseTrait.php
ResponseTrait.php	APPPATH/System/HTTP/ResponseTrait.php
Result.php	APPPATH/System/Database/MySQLi/Result.php
ResultInterface.php	APPPATH/System/Database/ResultInterface.php
RichRenderer.php	APPPATH/System/ThirdParty/Kint/Renderer/RichRenderer.php
RouteCollection.php	APPPATH/System/Router/RouteCollection.php
RouteCollectionInterface.php	APPPATH/System/Router/RouteCollectionInterface.php
Router.php	APPPATH/System/Router/Router.php
Router.php	FCPATH/Fcms/Library/Router.php
RouterInterface.php	APPPATH/System/Router/RouterInterface.php
Routes.php	APPPATH/Config/Routes.php
Routes.php	APPPATH/Extend/Routes.php
Routes.php	APPPATH/System/Config/Routes.php
Routes.php	APPPATH/System/Debug/Toolbar/Collectors/Routes.php
Security.php	FCPATH/Fcms/Library/Security.php
Seo.php	FCPATH/Fcms/Library/Seo.php
Service.php	FCPATH/Fcms/Core/Service.php
Services.php	APPPATH/Config/Services.php
Services.php	APPPATH/System/Config/Services.php
Show.php	FCPATH/Fcms/Control/Show.php
Text.php	FCPATH/Fcms/Field/Text.php
TextRenderer.php	APPPATH/System/ThirdParty/Kint/Renderer/TextRenderer.php
Textarea.php	FCPATH/Fcms/Field/Textarea.php
Timer.php	APPPATH/System/Debug/Timer.php
Timers.php	APPPATH/System/Debug/Toolbar/Collectors/Timers.php
Toolbar.php	APPPATH/Config/Toolbar.php
Toolbar.php	APPPATH/System/Debug/Toolbar.php
URI.php	APPPATH/System/HTTP/URI.php
UserAgent.php	APPPATH/System/HTTP/UserAgent.php
UserAgents.php	APPPATH/Config/UserAgents.php
Utils.php	APPPATH/System/ThirdParty/Kint/Utils.php
Version.php	FCPATH/My/Config/Version.php
View.php	APPPATH/Config/View.php
View.php	APPPATH/Extend/View.php
View.php	APPPATH/System/Config/View.php
View.php	APPPATH/System/View/View.php
View.php	FCPATH/Fcms/Core/View.php
Views.php	APPPATH/System/Debug/Toolbar/Collectors/Views.php
custom.php	/webdata/wei/config/custom.php
database.php	/webdata/wei/config/database.php
domain_app.php	/webdata/wei/cache/config/domain_app.php
domain_client.php	/webdata/wei/cache/config/domain_client.php
hooks.php	/webdata/wei/config/hooks.php
index.php	/webdata/wei/index.php
init.php	APPPATH/System/ThirdParty/Kint/init.php
init_helpers.php	APPPATH/System/ThirdParty/Kint/init_helpers.php
lang.php	/webdata/wei/api/language/zh-cn/lang.php
site.php	/webdata/wei/cache/config/site.php
system.php	/webdata/wei/cache/config/system.php
template_DS_pc_DS_default_DS_home_DS_footer.html.cache.php	/webdata/wei/cache/template/template_DS_pc_DS_default_DS_home_DS_footer.html.cache.php
template_DS_pc_DS_default_DS_home_DS_header.html.cache.php	/webdata/wei/cache/template/template_DS_pc_DS_default_DS_home_DS_header.html.cache.php
template_DS_pc_DS_default_DS_home_DS_show.html.cache.php	/webdata/wei/cache/template/template_DS_pc_DS_default_DS_home_DS_show.html.cache.php
url_helper.php	APPPATH/System/Helpers/url_helper.php

File:	/webdata/wei/dayrui/Fcms/Control/Show.php
App:	/
Controller:	show
Method:	index
URI:	show/index
URL:	http://wei.vialancer.com/index.php?c=show&id=27

Datetime	Status	Method	URL	Content-Type	Is AJAX?
2023-07-25 14:40:22	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 14:40:18	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:35	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:33	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:31	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:29	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:25	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:20	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:18	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:16	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:12	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:06	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:50:03	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:49:39	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 11:49:36	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 09:50:02	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 09:36:57	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 09:35:42	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-25 09:33:16	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No
2023-07-24 17:45:43	200	GET	http://wei.vialancer.com/	text/html; charset=UTF-8	No

Cookie	pgv_pvi=2798497912
Accept-Language	zh-CN,zh;q=0.9
Accept-Encoding	gzip, deflate
Referer	http://wei.vialancer.com/index.php?c=category&id=12
Accept	text/html,application/xhtml+xml,application/xml;q=0.9,image/avif,image/webp,image/apng,/;q=0.8,application/signed-exchange;v=b3;q=0.7
User-Agent	Mozilla/5.0 (Windows NT 10.0; Win64; x64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/113.0.0.0 Safari/537.36
Upgrade-Insecure-Requests	1
Connection	keep-alive
Host	wei.vialancer.com

CodeIgniter Version:	4.0.5
PHP Version:	7.2.16
PHP SAPI:	fpm-fcgi
Environment:	development
Base URL:	http://wei.vialancer.com/
Timezone:	PRC
Locale:	en
Content Security Policy Enabled:	No

Time	Event Name	Times Called
4.91 ms	pre_system	1
0.05 ms	dbquery	5

省部共建国重室王开拓团队在CTAB改性偏高岭土聚合物微球对TcO4−/ReO4−的选择性吸附和回收方面取得进展

友情链接

联系我们

联系我们

4.0.5

Database (5 Queries across 0 Connection)

Views

运行时间：0.01ms

模板文件

引用提示

模板变量

Files ( 148 )

Routes

Events

History

View Data

Session User Data

Request ( HTTP/1.1 )

$_GET

Headers

Cookies

Response ( 200 - OK )

Headers

System Configuration