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The team of Professor Wan Lingyu: Extraordinary Photoexcitation of Semimetal 1 T'-MoTe2 inducing Ultrafast Charge Transfer in lateral 2D Homojunction

Time: July 15, 2024 Click:

In July 2024, The team of Professor Wan Lingyu from SKL is entitled "Extraordinary Photoexcitation of Semimetal 1 T'-MoTe2 inducing Ultrafast Charge Transfer in lateral 2D Homojunction" was published in the Nano Energy.

Exploring novel and more efficient photoexcitation transition mechanisms in two-dimensional transition metal dichalcogenides (TMDCs) is crucial for the advancement of high-performance optoelectronic devices. In this study, an extraordinary photoluminescence (PL) phenomenon is discovered that originates from a vertical transition between specific bands in the X-point energy valley of K-space in multilayer Weyl semi-metal monoclinic (1T') MoTe2 without a gap structure. This effective transition is independent of the bandgap and is unaffected by the number of layers in 1T'-MoTe2, breaking the limitations of traditional TMDCs semiconductor materials and promoting the development of advanced two-dimensional (2D) semimetal-based optoelectronic devices. In a lateral multilayer 1T'-MoTe2-2H hetero-phase homojunction, a record ultrafast transfer of photogenerated charges up to 25 fs is achieved. The highly efficient interband transition, small conduction band energy level difference (less than 100 meV), and exceptionally strong e-p coupling synergistically promote the ultrafast transfer of photo-generated charges. Together with the merits of multilayer 1T'-MoTe2 such as higher carrier densities and lower resistance, these findings open the door to potentially ultra-high performance optoelectronic applications.